Open a Bugzilla Account
If you do not already have one, you should open an account on bugs.kde.org. This will enable you to log in and comment on bugs.
Join the Mailing List and IRC Channel
You should join the bugsquad mailing list to keep up to date on the latest bugsquad happenings. We also gather in #kde-bugs on irc.freenode.net where you are welcome to ask any questions you have.
Pick a Bug to Triage
Choose a bug to triage. Pick any bug you like - a good place to start is with an application you use regularly and are familiar with. You can use bugzilla's query interface to search for bugs to triage.